New alloy could be a way to recycle CO2

By Brandi Jefferson-Wustl

A two-dimensional alloy material made from five metals acts as an excellent catalyst for reducing CO2 into CO, research indicates.

The research, from the lab of Rohan Mishra, assistant professor in the department of mechanical engineering and materials science at the McKelvey School of Engineering at Washington University in St. Louis, appears in the journal Advanced Materials.

“We’re looking at transforming carbon dioxide, which is a greenhouse gas, into carbon monoxide,” Mishra says. “Carbon monoxide can be combined with hydrogen to make methanol. It could be a way to take CO2 from the air and recycle it back into a hydrocarbon.”

The basis of this innovation is a class of materials known as transition metal dichalcogenides (TMDCs)—they include transition metals and a chalcogen, which includes sulfur, selenium, and tellurium. When an alloy contains more than three metals at near equal ratios, it’s said to be “high entropy.” Hence the wordy name of the material developed in Mishra’s lab: high-entropy transition metal dichalcogenides.

Alloy combinations

TMDCs are not new. There has been interest in similar two-dimensional forms of these materials due to their unique optical and electronic properties, Mishra says. But he had a suspicion they could be used for something else.

“We’ve been looking at these, too, but exploring their potential for electrocatalysis,” acting as a catalyst to facilitate chemical reactions. As they are effectively two-dimensional (about three atoms thick), they make for efficient catalysts; reactions occur on the surface of a material, and a two-dimensional material has a lot of surface area, and not much else. In an earlier study, also in the journal Advanced Materials in 2020, the group had shown that two-metal TMDC alloys showed improved catalytic activity over individual TMDCs. “This led us to the question, can adding more metals to these alloys make even better catalysts?” Mishra says.

With 10 applicable transition metals and three chalcogens, there are 135 two-metal and 756 five-metal possible TMDC alloys. However, just like oil and water, not all combinations will mix together to form a homogenous alloy.

“Without guidance from computations, experimentally determining which elemental combinations will give an alloy becomes a trial-and-error process that is also time consuming and expensive,” Mishra explains.

The alchemist in this case was John Cavin, a graduate student in Washington University’s physics department.

In the previous work, Cavin had shown which two transition metals can be combined, and at what temperatures, to form binary TMDCs alloys.

“The question was, ‘Could we even synthesize a TMDC alloy that had that many components?’” Cavin says. “And will they improve the reduction of CO2 into CO?”

Which will catalyze CO2?

To find out, Cavin used quantum mechanical calculations to predict which combinations were most likely to improve the material’s ability to catalyze CO2. Then he had to go further to determine if the material would be stable, but had no tools to do so. So, he developed one himself.

“I had to develop a thermodynamic model for predicting stable high-entropy TMDC alloys from the quantum mechanical calculations,” Cavin says. These calculations involved considerable supercomputing resources, which the Extreme Science and Engineering Discovery Environment network made available.

After years of development, the resulting analysis was sent to experimental collaborators at the University of Illinois at Chicago.

“At UIC, they could synthesize the materials that we predicted would form a high-entropy TMDC alloy,” Mishra says. “Furthermore, one of them showed exceptional activity.”

They may have other uses, too. UIC synthesized three of the four different TMDC alloys and will continue to analyze them.

“These are new materials, they have never before been synthesized,” Mishra says. “They may have unanticipated properties.”

The work stems from a DMREF grant from the National Science Foundation as part of the Materials Genome Initiative that President Barack Obama launched in 2011 to create policy, resources, and infrastructure that support US institutions to discover, manufacture, and deploy advanced materials efficiently and cost-effectively. The NSF provided support for the current work.

Source: Washington University in St. Louis

This article appeared on the Futurity website at https://www.futurity.org/alloy-five-metals-catalyze-co2-2591382-2/?utm_source=rss&utm_medium=rss&utm_campaign=alloy-five-metals-catalyze-co2-2591382-2


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